Enhancing properties of lead-free ferroelectric BaTiO3 through doping

Lead-free BaTiO3 nanowires-based flexible nanocomposite generator.

We have synthesized BaTiO3 nanowires (NWs) via a simple hydrothermal method at low temperature and developed a lead-free, flexible nanocomposite generator (NCG) device by a simple, low-cost, and scalable spin-coating method. The hydrothermally grown BaTiO3 NWs are mixed in a polymer matrix without a toxic dispersion enhancer to produce a piezoelectric nanocomposite (p-NC). During periodical and...

Inverse barocaloric effects in ferroelectric BaTiO3 ceramics

Dielectric and piezoelectric properties of sodium lithium niobate Na1−xLixNbO3 lead free ferroelectric ceramics

High density sodium lithium niobate lead free ceramics near the morphtropic phase boundary [NaxLi1−xNbO3, (LNN), x=0.12] were prepared by the solid state reaction method. XRD patterns showed that the lattice structures were changed after polarization. The temperature dependence of the dielectric constant and dielectric loss, pyroelectric coefficient and DSC curves of LNN ceramics showed that th...

Periodic Slab LAPW Computations for Ferroelectric BaTiO3

Linearized augmented plane wave (LAPW) calculations are performed for periodic (001) and (111) slabs of BaTiO3 to understand the effects of surfaces on ferroelectric BaTiO3. The (111) slab is found to be much less stable than the (001) slab. The average surface energies are respectively 3700 erg/cm and 1600 erg/cm. The depolarization field is sufficiently large in the ideal unrelaxated slab to ...

Thick lead-free ferroelectric films with high Curie temperatures through nanocomposite-induced strain.

Ferroelectric materials are used in applications ranging from energy harvesting to high-power electronic transducers. However, industry-standard ferroelectric materials contain lead, which is toxic and environmentally unfriendly. The preferred alternative, BaTiO(3), is non-toxic and has excellent ferroelectric properties, but its Curie temperature of ∼130 °C is too low to be practical. Strain h...